2021
DOI: 10.3390/ma14020257
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Effect of Radiation-Induced Cross-Linking on Thermal Aging Properties of Ethylene-Tetrafluoroethylene for Aircraft Cable Materials

Abstract: The effects of electron beam irradiation on ethylene-tetrafluoroethylene copolymer (ETFE) were studied. Samples were irradiated in air at room temperature by a universal electron beam accelerator for various doses. The effect of irradiation on samples and the cross-linked ETFE after aging were investigated with respect to thermal characteristics, crystallinity, mechanical properties, and volume resistivity using thermo-gravimetric analysis (TGA), differential scanning calorimeter (DSC), universal mechanical te… Show more

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Cited by 7 publications
(4 citation statements)
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“…an increase in crystallinity [11,[28][29][30]. This is consistent with the XRD analysis of the crystallization behavior of the PPS/GF composites at different cooling temperatures.…”
Section: Thermal Properties Of Pps/gf Compositessupporting
confidence: 86%
See 1 more Smart Citation
“…an increase in crystallinity [11,[28][29][30]. This is consistent with the XRD analysis of the crystallization behavior of the PPS/GF composites at different cooling temperatures.…”
Section: Thermal Properties Of Pps/gf Compositessupporting
confidence: 86%
“…As shown in Figure 3, the melting points (T m ) and crystallization temperatures (T c ) of the PPS composites at each cooling temperature exhibited similar trends and gradually increased. The higher the cooling temperature, the finer were the densely stacked crystals; moreover, the melting enthalpy increases, resulting in an increase in crystallinity [11,[28][29][30]. This is consistent with the XRD analysis of the crystallization behavior of the PPS/GF composites at different cooling temperatures.…”
Section: Thermal Properties Of Pps/gf Compositessupporting
confidence: 85%
“…This is because the linear or branched molecular structures of thermoplastics become more brittle during thermal aging [ 36 ]. Researchers attributed this to the cross-linking and crystallinity, which depended on the temperature and the exposure time, as reported by Zhang et al [ 37 ] and Lee et al [ 38 ]. Molecular chain scission, post-crosslinking, and crystallinity increment also occur in the GF/PPS composite samples during thermal aging [ 39 ].…”
Section: Resultsmentioning
confidence: 84%
“…According to the thermogravimetric analysis of X-ETFE insulation materials for aviation in Morelli et al, 30 Zen et al, 31 and Zhang et al 32 the X-ETFE insulation materials begin to decompose when the temperature reaches 350°C, and slight discoloration occurs on the surface of the material. When the temperature reaches 550°C, the decomposed insulating material is almost completely gasified.…”
Section: Resultsmentioning
confidence: 99%