2021
DOI: 10.1016/j.ijhydene.2020.07.222
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Effect of reaction conditions and surface characteristics of Ru/CeO2 on catalytic performance for ammonia synthesis as a clean fuel

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Cited by 28 publications
(8 citation statements)
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“…16,17 Importantly, both experiments and computations showed that Ru-based catalysts are promising candidates for producing NH 3 under mild reaction conditions. [18][19][20] This high activity for Ru-based catalysts is ascribed to the balance between Ru-N and Ru-H interactions, where the weak Ru-N interactions are insufficient to dissociate the N-N bond, and the strong Ru-N interactions result in N surface poisoning. [21][22][23] In addition, to reduce costs and increase catalytic sites, dispersing noble-metals on the carrier material with a high specic surface area is a dramatic approach.…”
mentioning
confidence: 99%
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“…16,17 Importantly, both experiments and computations showed that Ru-based catalysts are promising candidates for producing NH 3 under mild reaction conditions. [18][19][20] This high activity for Ru-based catalysts is ascribed to the balance between Ru-N and Ru-H interactions, where the weak Ru-N interactions are insufficient to dissociate the N-N bond, and the strong Ru-N interactions result in N surface poisoning. [21][22][23] In addition, to reduce costs and increase catalytic sites, dispersing noble-metals on the carrier material with a high specic surface area is a dramatic approach.…”
mentioning
confidence: 99%
“…[24][25][26] Some studies indicate that the characteristics of the support material, such as basicity and electronegativity have far-reaching inuence on the catalytic activity of Ru-based catalysts for NH 3 synthesis. 20,27 Therefore, the design of reciprocal interface between Ru-based catalysts and functionalized MOF sheets is very worthy of obtaining superior NO…”
mentioning
confidence: 99%
“…The fastest-growing field of development in the world is nanotechnology, and researchers are involved in developing new nanomaterials through new and straightforward processes [1][2][3][4][5][6][7]. In the past few decades, the field of nanotechnology has shown remarkable successes, with various methodologies devised for the synthesis of nanoparticles of unique shapes and dimensions in compliance with specific requirements [8][9][10][11][12][13][14][15].…”
Section: Introductionmentioning
confidence: 99%
“…The changes in the composition of size or surface can affect the physical and chemical characteristics of the nanoparticles [14,15]. Metal nanoparticles have been used in many industries in recent decades due to their wide variety of applications [16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32][33]. The physical, chemical, and electrical properties of nanoparticles dramatically change at a specific size range (1-100 nm).…”
Section: Introductionmentioning
confidence: 99%