Effect of recycled oyster shell powder on hydration and strength development of magnesium phosphate cement

Abstract

Using oyster shell powder (OSP) to prepare magnesium phosphate cement (MPC) not only reduces the pollution caused by the wasted oyster shell disposal but also in favor of the development of ecological cement. The effect of OSP on the hydration and strength development of MPC was studied. An axial compression experiment including 45 cuboid specimens was executed to investigate the compressive strength, failure mode, stress-strain relationship, and energy absorption of MPC mixing with different mass contents (0% to 12%) of OSP under the curing times of 7, 14, and 28 d. Scanning electron microscopy (SEM), X-ray diffraction (XRD) as well as energy dispersive spectroscopy (EDS) were utilized for measuring the variation of MPC microstructure and hydration products caused by OSP. Results indicated that a new reactant CaHPO4·2H2O was formed, which optimized matrix strength. The substitution of OSP could reduce the cost of MPC by 2%∼9% without decreasing the strength. The compressive strength of MPC increases with the increase of OSP content. Compared with MPC without OSP, the compressive strength of OSP with a dosage of 3% is increased by 6%. However, with the continuous increase of OSP content, the compressive strength gradually decreases. Similarly, the elastic modulus of MPC increases first and then decreases with the increase of OSP content.