The change in material dimensional will lead to the decline of instrument accuracy and reliability. In this paper, the characterization and analysis of the lattice constant, precipitates, and dislocation density of the material by X-ray diffraction (XRD) and transmission electron microscopy (TEM) reveals the reason why the relative dimensional change in the rolled 2024Al is one order of magnitude lower than that of the as-cast 2024Al during isothermal aging. Compared with as-cast 2024Al, the dislocation density of rolled 2024Al is higher, the lattice constant decreases less before and after aging, and the precipitates have orientation and more content, resulting in the dimensional change in rolled 2024Al being smaller than that of as-cast 2024Al. In addition, two main reasons for decreasing the dimensional change in rolled 2024Al are discussed: the decrease in lattice constant, the formation and growth of the S phase before and after aging.