“…Thus the IR study indicates the presence of Mn 4 þ ions in the material which could be due to cation vacancies in the sample [18,36]. The peaks observed at 524 cm À 1 and 646 cm À 1 correspond to the distortion vibration at octahedral sites and the characteristic tetrahedral stretching vibration respectively [8,9,29,[33][34][35]. The absorption band at 577 cm À 1 is close to the reported value for Mn 2 O 3 [15].…”
Section: Ftir Analysissupporting
confidence: 75%
“…The result of EDX analysis ( Fig. 3(b)) shows the presence of only Mn and O ensuring the absence of any impurity [29]. [15].…”
“…Thus the IR study indicates the presence of Mn 4 þ ions in the material which could be due to cation vacancies in the sample [18,36]. The peaks observed at 524 cm À 1 and 646 cm À 1 correspond to the distortion vibration at octahedral sites and the characteristic tetrahedral stretching vibration respectively [8,9,29,[33][34][35]. The absorption band at 577 cm À 1 is close to the reported value for Mn 2 O 3 [15].…”
Section: Ftir Analysissupporting
confidence: 75%
“…The result of EDX analysis ( Fig. 3(b)) shows the presence of only Mn and O ensuring the absence of any impurity [29]. [15].…”
“…Since smaller XRD peak width indicates a larger grain size [39], Sample CZTS shows slightly narrower XRD peaks than Sample ACZTS suggesting that Sample CZTS has a larger average grain size than Sample ACZTS [24]. respectively.…”
“…It should be noted that a mixture of m-and t-LaVO 4 can be obtained when the pH N 2. The grain size calculated on the (120) diffraction maximum from the half-width of diffraction peaks using Scherrer's formula [40,41] was found to be 60 nm. Fig.…”
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