Effect of CNTs / nano‐TiO 2 hybrid system on the drop‐weight impact response of Kevlar fiber/epoxy composites

The global composite industry generates large quantities of waste which mostly ends up in landfills due to a lack of established end‐use applications for multiple waste streams. The scrap from end‐of‐life (EoL) includes manufacturing waste such as dry chopped fiber tows, loose fibers, shredded fibers from fabric textile operations, cured/semi‐cured prepregs, and fully cured composite structure waste from aircraft, automobiles, wind blades, boats, and pressure vessels. In this work, different composite waste streams were reduced to shredded intermediates, followed by simple blending, and subjected to wet compression molding to produce composite panels. The panels/plaques were tested for mechanical properties (flexure and impact), fiber‐matrix wet‐out, and property bounds. It was found that wet‐compression molding was a viable and scale‐able approach to produce recycled panels from EoL composites shredded scrap. Furthermore, full‐scale size panels for use in truck bodies and intermodal shipping container flooring were manufactured and their impact resistance was tested using a drop weight impact test. They were tested both for high‐ and low‐velocity load. In the case of high‐velocity load, the average impact load was 14,673 N; the average absorbed energy was 101.6 J; the average elastic energy was 11.7 J and the impact resistance was 1065 J/m. In the case of the low‐velocity drop weight impact test, it was found that the average impact load was 7877.358 N; the average absorbed energy was 9.718 J; the average elastic energy was 9.14 J, and the impact resistance was 184.1 J/m. The shredded composite was shown to be a candidate material for the manufacture of truck bodies and intermodal containers’ flooring panels.Highlights By using shredded intermediates from different composite waste streams, it is possible to manufacture composite panels. Wet–compression process is an appropriate technique for manufacturing recycled fiber composite panels. Regardless of the source of scrap, the mechanical properties of the produced composite panels were improved. The recycling process technology can be transformed to commercial scale to produce full‐size transportation flooring panels. A product pathway is established in consideration of lower cost and improved recyclability.

Section: F I G U R Econtrasting

confidence: 86%

Effect of recycled fibers and shredded intermediates variation on the mechanical properties and energy absorption of fiber‐reinforced composite panels

Vaidya,

Fono Tamo,

Chahine

et al. 2023

“…However, aramid fibers are rigid molecules with a relatively high orientation and crystallization state, the surface is smooth and inert, so the interfacial adhesion to most industrial composite resins is weak 11 . Aramid fiber is widely used as a reinforcing agent in composites in the form of fiber bundles, continuous filaments, pulp, woven textile material, short fibers, powder, etc 12–15 . Therefore, to improve the interfacial connection, different methods of modifying the fiber surface are used, which traditionally favor either physical or chemical adhesion with the matrix.…”

Section: Introductionmentioning

confidence: 99%

Composites based on polymeric blends reinforced with TiO₂ modified aramid fibers

Pelin,

Sonmez,

Pelin

et al. 2024

The paper presents a study on composites based on 50:50 (PP:LLPE‐g‐MA) reinforced with 0.5, 1, and 2 wt% aramid fibers unmodified/modified with TiO2, processed by melt compounding. Micronic aramid fibers were acetone washed to remove impurities and treated with Ti(IV)isopropoxide precursor via sol–gel method, adding microcellulose for TiO2 particle dimension control. Composites were hot‐pressed into 4 mm‐thick plates for sampling and 0.5 mm‐thick sheets for thermoforming. All composites were successfully thermoformed, fibers‐based samples showing improved thermoforming ability without wrinkling. Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and Energy dispersive X‐ray spectroscopy (EDS) analysis confirmed the formation of TiO2 particles on the fiber surface. Optical microscopy, SEM and FTIR analysis exhibit the fibers' strong embedment into the matrix due to physical interlocking, generating surface defect reduction. Water absorption decreased from 0.195% (control) to 0.075 and 0% for 1 TiO2 and 2 TiO2 samples, due to material compactization. Contact angles increased from 95.18° (Control) to 108° (1 TiO2) and 112.89° (2 TiO2). The highest flexural strength and modulus were exhibited by 1 TiO2 sample that increased by 44.88% and 47.6% compared to the control sample, due to higher intrinsic rigidity of fibers and TiO2 modifying surface rugosity and phase interaction. The impact strength of the control sample improved by 139% compared to PP due to brittleness reduction, 1 TiO2 by 209% compared to PP, 29% compared to the control sample. The results and excellent thermoformability recommend the materials for encapsulation of electronic/expensive parts in automotive or drone applications, offering viable, facile, rapid, and cost‐effective solutions to easily replace damaged parts.Highlights Aramid fibers were successfully modified using isopropoxide precursor; Strong embedment of fibers in the polymer diminishes crack propagation/damage; Improved impact and bending properties and water contact angle; The composites showed a high ability to thermoform into complex shapes; Potential to replace non‐reusable materials as encapsulation solutions.

Development and characterization of titanium oxide filled ramie fiber based hybrid composites

Mahapatra

Satapathy

2023

This investigation aims to develop and characterize a class of multi‐phase hybrid composites consisting of bi‐directional ramie fibers, epoxy resin and micro‐sized titania (TiO2) particles in different proportions. Conventional hand layup technique is followed for fabrication of these composite slabs with fixed fiber fraction but different filler loadings of 0, 10, 20, and 30 wt%. The composites are subjected to different physical, compositional, and mechanical characterization tests under controlled laboratory conditions. The microstructural features of the composites are studied using scanning electron microscopy and stereo‐microscopy. For the compositional analysis, Fourier transform‐infrared spectroscopy (FTIR) and X‐ray diffraction (XRD) technique are adopted. The functional groups present in the constituent materials are identified and so also the different phases in the composites. The different characterization tests reveal that with the incorporation of hard titania particles, the tensile, flexural, inter‐laminar shear strength, hardness, and impact strength improve. Similarly, the density and moisture absorption behavior are also found to be greatly affected by the inclusion of fillers. Armed with reasonably good mechanical properties and improved hardness, these epoxy‐ramie composites filled with titania micro‐particles may possibly find applications as functional materials in potential areas like wear prone situations.Highlights Hybridization of ramie‐epoxy composite by additional reinforcement of TiO2. Physical properties of the composites are affected by the inclusion of fillers. Mechanical properties of composites improved with filler content. The developed composites can be used for wear resistant applications.