One of the important findings of the recent decades in the construction industry is composite sandwich panels (CSPs), which have benefits of being lightweight, providing thermal insulation, and aiding the economy; they are transforming continuously through many add-ons as needed by the industry. With the demand for sustainability in the field, CSPs need structural and sustainable enhancement. In the present study, an approach for the same has been attempted with geopolymer concrete (GPC) and novel nylon fibre to improve the sustainability and structural benefits, respectively. With various material combinations including GPC reinforced with fibres, six CSPs were cast and studied. The inherent limitations of GPC have been addressed by the nylon fibre reinforcement instead of using steel fibres, which have a similar strength, considering the aim of maintaining the density of the wythe material. A comparison of the flexural behaviour of the CSPs through the parameters of load–deflection, ductility, and toughness was made using the four-point loading test. The results of the test specify that the fibres enhance the performance of the CSPs under flexural loading.