Aqueous suspensions of magnesium hydroxide are shown to exhibit low zeta potential behaviour and highly complex settling dynamics. Two distinct regimes of hindered settling behaviour are observed either side of a threshold concentration, φ * , of 2.38 % v/v, which is considerably below the gel point, φ g , observed at 5.4 ± 1.6 % v/v.The low concentration regime was characterised by a very large Richardson and Zaki exponent of 146, a factor of 10 larger than that of the high concentration regime. Michaels and Bolger analysis of the low concentration regime implies settling governed by large, low density macro-aggregates of 138-147 µm diameter and low intra-aggregate packing fractions in the order of 0.05, which is in good agreement with in-situ particle char-