Aqueous solutions of xanthan, which is produced by Xanthomonas campestris, are used as viscosity control agents for various food materials. The viscosity is dependent on the environmental conditions affecting the xanthan macromolecule. Moreover, the viscosity frequently depends on the methods used to measure the shear rate during operation. For practical applications of xanthan solutions, the background of this phenomenon should be made clear. The solutions used in this study were prepared by dissolving xanthan in water or in an aqueous salt solution (NaCl, 1 M). The viscosity was then measured using a rotational viscometer. For the aqueous solution of xanthan, the viscosities measured at increasing shear rates showed shear thickening in the low-shear-rate region. On the other hand, no discrepancy between the behaviors was observed when xanthan was dissolved in the salt solution. This paper discusses the aforementioned viscosity behavior using a dispersion model of polymers with contact sites for the solutions.