The results are given of an investigation of the effect of explosive pressing on the structure and properties of Phenylone S3. The optimum pressure of explosive pressing and the optimum temperature of subsequent sintering of preforms of 3-10 mm thickness were determined. The thermomechanical properties and the structural changes of Phenylone were investigated after shock-wave and heat treatments. The physicomechanical properties of Phenylone S3 after explosive pressing are compared with those of Phenylone S2 produced by hot pressing. Phenylone (a trade name used in Russia for the linear aromatic [-NHC 6 H 4 NHOCC 6 H 4 CO-] n polyamide polymeta-phenylene isophthalamide) possesses a fairly high prolonged temperature service, high hardness, rigidity, and strength, and good antifriction and other properties. On account of this, Phenylone is used mainly for the manufacture of components and assemblies undergoing severe service conditions.