Polymers are among the most important materials and their applications permeate all areas of production and life. [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16] They are essential, but they are also often seen as a modern-day scourge, especially in terms of their negative impact on the environment. 17-21 For example, tens of millions of tons of waste plastic particles are discarded into the ocean every year, negatively impacting marine biodiversity 22 ; not to mention the large amounts of fossil fuels used to produce these plastics. The increasingly serious environmental pollution problem has led to a worldwide plastic restriction and ban, and the use of renewable and environmentally friendly biodegradable polymers and its composites is considered to be one of the effective ways to solve this problem. [23][24][25][26][27][28][29][30][31][32] The application of biodegradable polymers and its composites can not only effectively solve the problem of white pollution and reduce the dependence of synthetic polymers on petroleum resources but also help to reduce excessive greenhouse gas emissions and promote the high-value utilization of biomass resources, which is in line with the goal of sustainable development and the core concept of circular economy. [33][34][35][36][37][38] However, the current challenge is that compared with general-purpose plastics and engineering plastics, biodegradable polymers and its composites still have many performance bottlenecks, such as low/limited strength, poor toughness, low modulus, poor heat resistance, and lack of functionality, which greatly limit their application in high value-added and high performance requirements. 39 Therefore, the processing of high-performance biodegradable polymers and its composites has become an important research area in polymer science and technology today.For a biodegradable polymeric materials with known physical properties, morphology control is an important way to achieve high-performance materials without changing the proximal structure, composition, and components of the molecular chain. 40 Traditional polymer processing techniques, such as extrusion, injection molding, blow molding, compression molding and spinning, have mild effects on the morphological structure of polymeric materials. They are not able to significantly