2021
DOI: 10.1002/zaac.202000398
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Effect of single variable factor of electron‐acceptor on the luminescence quantum yield of terbium complex

Abstract: Two series of terbium complexes of Tb 2 (4-BMBA) 6 (phen) 2 (TbÀ Br, 4-BMBA = 4-Br-3-methylbenzoic acid, phen = 1,10-phenanthroline) and Tb 2 (4-IMBA) 6 (phen) 2 (TbÀ I, 4-IMBA = 4-I-3methylbenzoic acid) are synthesized by varying the single factor of electron-acceptor property of substituent group Br and I at para-position of 3-methylbenzoic acid. They crystalize in the same space group, ligand and metal ions are arranged in the same mode. Interestingly, the luminescence quantum yield (QY) of TbÀ Br is greate… Show more

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