2019
DOI: 10.1016/j.eurpolymj.2019.03.016
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Effect of solvents on the RAFT polymerization of N-(2-hydroxypropyl) methacrylamide

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Cited by 20 publications
(9 citation statements)
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“…They have been used in drug delivery systems as drug carriers and polymer-drug conjugates, as well as gene delivery carriers due to their hydrophilic and non-immunogenic characteristics. The efficacy and biocompatible properties of these polymers have also been reported [12][13][14][15][16][17][18][19][20][21][22].…”
Section: Introductionmentioning
confidence: 85%
“…They have been used in drug delivery systems as drug carriers and polymer-drug conjugates, as well as gene delivery carriers due to their hydrophilic and non-immunogenic characteristics. The efficacy and biocompatible properties of these polymers have also been reported [12][13][14][15][16][17][18][19][20][21][22].…”
Section: Introductionmentioning
confidence: 85%
“…pentanoic acid (ECT) was synthesized according to the previous report. [38] All other reagents and chemicals were purchased from commercial sources and were used as received without further purification.…”
Section: Discussionmentioning
confidence: 99%
“…We believe that this discovery offers considerable scope for the design of new stimuliresponsive polymers and to widen the applicability of these zwitterionic "smart" materials agent (synthesized according to the previous report [38]), and different ester end-groups were introduced by esterification of ECT by alcohol with different alkyl chain length.…”
Section: Introductionmentioning
confidence: 90%
“…The choice of solvent mixtures was respectively related to previously described (co-)polymerisations of nucleobase analogues and pHPMA. 18,24,25,[33][34][35][36] Using a 9 : 1 1,4-dioxane/H 2 O mixture gave a high conversion (94%) of the G-based polymer ( piGPMA), while the conversion of cytidine-based polymer ( piCPMA) was lowered to 34% with the same solvent mixture. On the other hand, the conversion of piCPMA was increased to 40% and of the piGPMA was decreased to only 70% in 8 : 2 DMF/H 2 O. Polymerizations of nucleoside homopolymers and their monomer conversions were determined by comparing the integrals of the typical C-4 protons of piCPMA (δ 4.43 ppm) and piGPMA (δ 4.50 ppm) with the integrals of the monomer vinyl peaks of iCPMA (δ 5.64 ppm and 5.30 ppm) and iGPMA (δ 6.39 ppm and 5.61 ppm).…”
Section: Polymerizationmentioning
confidence: 99%