Copper-infiltrated sintered steel is a prominent area of research in the field of powder metallurgy, with a particular focus on enhancing impact toughness. In this study, sintered steels with varying pore structures were prepared using iron powders and infiltrated with copper to investigate their impact toughness. The results indicate a significant improvement in the impact toughness of the sintered steels with concentrated iron particle sizes. The density of the samples increased from 6.85g/cm³ to 7.55g/cm³ through copper infiltration. The large copper-phase sample with the particle size of 150μm exhibits an impact toughness as high as 41.09 J/cm², and its fracture morphology mainly shows transgranular fractures of large iron particles. It is 1.5 times that of the sample made from commercial iron powders which measured 27.46 J/cm². This enhancement is primarily attributed to the precipitation of γ-Fe within the large copper phase, thereby enhancing the copper phase and transferring the load into large iron particles. A brief mechanism of γ-Fe precipitation in the large copper-phase has been provided.