Effect of Stepwise Replacement of Non-Oxide to Oxide Group on Structural Properties of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M1"><mml:mrow><mml:msub><mml:mrow><mml:mtext>Bi</mml:mtext></mml:mrow><mml:mn mathvariant="bold">2</mml:mn></mml:msub><mml:msub><mml:mtext>O</mml:mtext><mml:mn mathvariant="bold">3</mml:mn></mml:msub></mml:mrow></mml:math>·LiF·<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M2"><mml:msub><mml:mtext>B</mml:mtext><mml:mn mathvariant="bold">2</mml:mn><

Arora, Susheel; Kundu, Virender; Goyal, D. R.; Maan, A. S.

doi:10.5402/2012/896492

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2013

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“…It leads to a decrease in the ionic conductivity. Third process is the formation of BO 2 F and B-F units reported by us earlier [17]. Formation of such units also results in the decrease in the number of hopable ions.…”

Section: Conductivitymentioning

confidence: 99%

DSC and DC Conductivity of Bi₂O₃ · LiF · B₂O₃ Glasses

et al. 2013

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Fluoroborate glasses with Bi 2 O 3 content and having compositions xBi 2 O 3 ⋅ (40-x )LiF ⋅ 60B 2 O 3 (x = 0, 5, 10, 15, and 20) are prepared using melt-quench technique. DSC characterization is carried out to observe glass transition temperature. Two such temperatures are observed for each of the reported samples. DC conductivity of the reported samples is studied with the variation in temperature from 313 K to 413 K by dividing this range into three regions, namely, low-, intermediate-, and high-temperature regions. DC conductivity responses for these temperature regions are explained using different conductivity models.

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Section: Conductivitymentioning

confidence: 99%