Effect of Substituents on the Triple Ion Formation from Various Ammonium or Guanidium Chlorides

Abstract

The triple ion formation from various ammonium or guanidium chlorides has been examined by conductometry in acetonitrile, benzonitrile, and propylene carbonate. The observed minimum in the Λ−C1/2 curve of diethylcyclohexylammonium chloride in benzonitrile could be reproduced in terms of a large formation constant of quadrupole complexes by computer simulations.