Effect of substitution of ZrO2 by SnO2 on crystallization and properties of environment-friendly Li2O–Al2O3–SiO2 system (LAS) glass-ceramics

Zhang, Jinhao; Huang, Jianghai; Yu, Yuanjie; Zhang, Zaili; Bai, Haitao; Huang, Yi-Zhou

doi:10.1016/j.ceramint.2022.04.101

Cited by 15 publications

(2 citation statements)

References 34 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…To achieve homogeneity in batch melting, especially in complex glass-ceramic systems, the glass will be quenched and remelted. Compositionally dependent melting temperatures are generally increased with added ZrO 2 in the range of, for example, 1400-1700 • C. 22 Then, the glass will be crystallized above the glass transition temperature (T g ) before it is prepared for characterization. This procedure is usually a two-part heat-treatment comprising of nucleation and growth periods.…”

Section: Glass-ceramic Processingmentioning

confidence: 99%

Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase

Shearer,

Montazerian,

Deng

et al. 2024

Int J Ceramic Engine & Sci

View full text Add to dashboard Cite

This article reviews promising studies on the design, manufacturing, microstructure, properties, and applications of glass‐ceramics containing ZrO2 and relevant glass‐ceramic matrix composites. After the addition of ZrO2 to a glass‐ceramic composition, it can persist in the residual glassy phase, facilitate nucleation, and/or precipitate as ZrO2 or another zirconate crystalline phase. Also, ZrO2‐reinforced or ZrO2‐toughened glass‐ceramics can be designed as composites. In this article, the term “ZrO2‐containing glass‐ceramics” encompasses all these scenarios in which ZrO2 is present. Such glass‐ceramics offer a wide range of applications in modern industries, including but not limited to architecture, optics, dentistry, medicine, and energy. Since S. Donald Stookey's discovery of glass‐ceramics in the early 1950s, the most important scientific efforts reported in the literature are reviewed. ZrO2 is commonly added to glass‐ceramics to promote nucleation. As a result, the role of ZrO2 in structural modification of residual glass and stimulating the nucleation in glass‐ceramic is first discussed. ZrO2 can also be designed into the main crystalline phase of glass‐ceramics, contributing achieving super high fracture toughness above 4 MPa·m0.5. Experimental and computational studies are reviewed in detail to elucidate how the transformation toughening and other mechanisms help to achieve such high values of fracture toughness. Sintered and glass‐ceramic matrix composites also show promise, where ZrO2 contributes to improved stability and mechanical properties. Finally, we hope this article will provoke interest in glass‐ceramic materials in both the scientific and industrial communities so that their tremendous technological potential in developing, for example, tough, thermally stable, transparent, and biologically compatible materials can be realized more widely.

show abstract

Section: Glass-ceramic Processingmentioning

confidence: 99%

Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase

Shearer,

Montazerian,

Deng

et al. 2024

Int J Ceramic Engine & Sci

View full text Add to dashboard Cite

show abstract

“…Kleebusch et al 17 also reported the oriented growth of β-quartz SS relative to ZrTiO 4 SS, indicating that the nucleating-agent-derived crystalline phase is closely related to the formation of the LAS-based crystalline phase. Using X-ray diffraction (XRD) and Rietveld refinement, Dressler et al, 18 Nishida et al, 19 and Zhang et al 20 demonstrated that co-doping with ZrO 2 and SnO 2 leads to a higher nucleation rate and enhanced formation of LAS-based crystalline phases, such as the β-quartz SS and β-spodumene SS, compared to the addition of ZrO 2 or SnO 2 alone. Dressler et al 18 also reported that the crystalline phase formed during heat treatment varies with the ratio of ZrO 2 and SnO 2 added.…”

mentioning

confidence: 99%

Effect of ZrSnO₄ solid solution on the crystallization behavior of Li₂O–Al₂O₃–SiO₂ glasses

Kajihara,

Hijiya,

Yoshida

et al. 2023

Int J of Appl Glass Sci

View full text Add to dashboard Cite

Herein, the crystallization behavior of a Li2O–Al2O3–SiO2 (LAS) glass system with the addition of ZrO2 and SnO2 as nucleating agents was investigated using X‐ray diffraction, differential scanning calorimetry, four‐dimensional scanning transmission electron microscopy, and X‐ray absorption fine‐structure measurements. At lower heat‐treatment temperatures, the addition of ZrO2 and SnO2 afforded a ZrSnO4 solid solution (SS), whereas at higher heat‐treatment temperatures, the ZrSnO4 SS decomposed, affording tetragonal ZrO2 and tetragonal SnO2. LAS‐based crystalline phases, such as β‐quartz and β‐spodumene phases SS, were formed after the formation of the ZrSnO4 SS. ZrSnO4 SS particles a few nanometers in size were present in contact with the β‐quartz SS particles a few dozen nanometers in size. This suggests that the ZrSnO4 SS served as a crystal nucleus for the β‐quartz SS, promoting its growth.This article is protected by copyright. All rights reserved

show abstract

Glass-Ceramics with High Strength and High Transmittance Obtained by Multi-Factor Controlling

Hu,

Rao,

Wang

et al. 2024

J. Wuhan Univ. Technol.-Mat. Sci. Edit.

View full text Add to dashboard Cite

Effect of substitution of ZrO2 by SnO2 on crystallization and properties of environment-friendly Li2O–Al2O3–SiO2 system (LAS) glass-ceramics

Cited by 15 publications

References 34 publications

Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase

Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase

Effect of ZrSnO₄ solid solution on the crystallization behavior of Li₂O–Al₂O₃–SiO₂ glasses

Glass-Ceramics with High Strength and High Transmittance Obtained by Multi-Factor Controlling

Contact Info

Product

Resources

About

Effect of substitution of ZrO2 by SnO2 on crystallization and properties of environment-friendly Li2O–Al2O3–SiO2 system (LAS) glass-ceramics

Cited by 15 publications

References 34 publications

Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase

Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase

Effect of ZrSnO4 solid solution on the crystallization behavior of Li2O–Al2O3–SiO2 glasses

Glass-Ceramics with High Strength and High Transmittance Obtained by Multi-Factor Controlling

Contact Info

Product

Resources

About

Effect of ZrSnO₄ solid solution on the crystallization behavior of Li₂O–Al₂O₃–SiO₂ glasses