INTRODUCTIONNowadays, nanoparticles such as silicon dioxide [1][2][3], Portland cement [4], and carbon nanotubes (CNT) [5,6] have been tested in ultra-high strength concretes in order to improve their performance. The results published in [7] show an optimum nano-silica content, i.e. the smallest quantity of nano-particles that leaded to the maximum compressive strength gain, for mixtures containing 0.5 wt% of silica nanoparticles. In [8], the maximum gain on compressive strength was observed for mixtures containing 2 wt% of nano-silica. The results published in [9] show a maximum gain on compressive strength for mixtures containing 2.82 wt% of nano-silica. In [10][11][12], the optimum content for mixtures containing 3 wt% of nano-silica was observed. In [13] the maximum compressive strength occurred for mixtures formulated with 4 wt% of nano-silica. Results published in [14] exhibit a tendency of linear increase on compressive strength, reaching the maximum strength for concretes formulated with 5 wt% of nanoparticles. In [15] the optimum nano-silica content was reached for mixtures containing 6% of nanoparticles. For large amounts of nanoCerâmica 63 (2017) [387][388][389][390][391][392][393][394] http://dx.doi.org/10.1590/0366-69132017633672037Effects of nano-silica on mechanical performance and microstructure of ultra-high performance concrete (Efeitos da nanossílica no desempenho mecânico e microestrutura de concretos de ultra-alta resistência) UEL, Londrina, PR thiagomendes@utfpr.edu.br, wellington.repette@gmail.br, pjlondrina@yahoo.com.br
AbstractThe use of nanoparticles in ultra-high strength concretes can result in a positive effect on mechanical performance of these cementitious materials. This study evaluated mixtures containing 10 and 20 wt% of silica fume, for which the optimum nano-silica content was determined, i.e. the quantity of nano-silica that resulted on the higher gain of strength. The physical characterization of raw materials was done in terms of particle size distribution, density and specific surface area. Chemical and mineralogical compositions of materials were obtained through fluorescence and X-ray diffraction. The mechanical performance was evaluated by compressive strength, flexural strength and dynamic elastic modulus measurements. The microstructural analysis of mixtures containing nano-silica was performed by X-ray diffraction, thermogravimetry, mercury intrusion porosimetry and scanning electron microscopy. Obtained results indicate an optimum content of nano-silica of 0.62 wt%, considering compressive and flexural strengths. This performance improvement was directly related to two important microstructural aspects: the packing effect and pozzolanic reaction of nano-silica. Keywords: ultra-high strength, nano-silica, mechanical performance, microstructure. silica, the maximum gain on mechanical properties for mixtures formulated with 10 wt% of silica nanoparticles was reported [16]. The flexural strength and elastic modulus present the same tendency for optimum nano-si...