Pure phases of zeolites Beta and ZSM-5 were synthesized from high silica raw kaolinite. Both zeolites were characterized by XRD, XRF, SEM and N2 adsorption/desorption isotherms. The acid forms of zeolites (H-zeolite) were used in the catalytic etherification of ethylene glycol with benzyl alcohol and with t-butanol. In the reaction of ethylene glycol with benzyl alcohol, ethylene glycol monobenzyl ether was the only detected product over H-ZSM-5, while in case of H-zeolite Beta, ethylene glycol monobenzyl ether and ethylene glycol dibenzyl ether were detected. The highest yield of ethylene glycol monobenzyl ether (58 %) was obtained from H-ZSM-5 prepared from raw kaolinite.