Effect of Temperature and Concentration on the Viscosity of Perchloric Acid

Loshali, Renu; Kandpal, N. D.

doi:10.14233/ajchem.2017.20812

Cited by 3 publications

(3 citation statements)

References 27 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The various solute-solvent interaction of hydrochloric acid in water has been reported 18 . The free energy of activation of viscous flow has been calculated using Erying viscosity equation 19 .…”

Section: Methodsmentioning

confidence: 99%

Viscometric Behavior of Concentrted Perchloric Acid

Loshali

Kandpal

2017

J. Chil. Chem. Soc.

Self Cite

View full text Add to dashboard Cite

Viscosity ƞ and density ρ of aqueous concentrated perchloric acid 1.0moldm −3 to 9.0moldm −3 were measured at 297.65K. The viscosity data were used to calculate the value of A and B-coefficient of Jones-Dole equation. The value of B-coefficient is positive which suggests the strong ion-solvent interaction in aqueous perchloric acid. The three concentration regions of perchloric acid having value of B-coefficient (measure of ion-solvent interaction or structure making capacity) in the order 1.0 to 4.0moldm −3 < 4.0 to 6.0moldm −3 < 6.0 to 9.0moldm −3 has been proposed.

show abstract

Section: Methodsmentioning

confidence: 99%

Viscometric Behavior of Concentrted Perchloric Acid

Loshali

Kandpal

2017

J. Chil. Chem. Soc.

Self Cite

View full text Add to dashboard Cite

show abstract

“…(i) k obs = 0.56B (6) These relations confirm the influence of B x -coefficient on rate of hydrolysis of ester catalyzed by HClO 4 . The similar study has been carried out for aqueous solution of concentrated hydrochloric acid 16 .…”

Section: Resultsmentioning

confidence: 97%

Catalytic and Viscometric Behavior of HClO4-H2O System

2016

Chem Sci Trans

View full text Add to dashboard Cite

The interaction parameters A x and B x were calculated using modified Jones-Dole equation. The three concentration region in HClO 4-H 2 O system were obtained which have been confirmed from kinetic data. To show the influence of interaction parameter on reaction rate, the hydrolysis of methyl acetate catalyzed by perchloric acid has been performed. The study is an illustrative model in the advancement of solution chemistry.

show abstract

“…Viscosities in aqueous solutions of different concentration have been observed and data has been utilized to determine the presence of molecular interaction like ion-ion, solute-solute and solute-solvent present in the system [1][2][3] . The viscosity parameters A and B explore solute-solute and solute-solvent interaction in different system.…”

Section: Introductionmentioning

confidence: 99%

Molecular Interaction of Aqueous Solution of 1-Propanol and 2-Propanol

2019

View full text Add to dashboard Cite

Viscosities (ƞ) of solutions of 1- propanol and 2-propanol have been determined in aqueous systems of varying composition (0.16-3.64 mol dm-3) at 298 K. The ƞ/ƞ0 data have been analyzed in the light of reduced Jone-Dole equation ƞ/ƞ0 = BC+1. The results in the regards to solute-solvent interaction in aqueous solutions of both the alcohols have been discussed in the terms of the value B. The result of study reveals that both the alcohols behave as the structure makers in the water. The result shows that solute-solvent type interaction of same magnitude exists in water-alcohol system.

show abstract

Effect of Temperature and Concentration on the Viscosity of Perchloric Acid

Cited by 3 publications

References 27 publications

Viscometric Behavior of Concentrted Perchloric Acid

Viscometric Behavior of Concentrted Perchloric Acid

Catalytic and Viscometric Behavior of HClO4-H2O System

Molecular Interaction of Aqueous Solution of 1-Propanol and 2-Propanol

Contact Info

Product

Resources

About