Nanowires
are an increasingly prevalent class of nanomaterials
in composites and devices, with arrays and other complex geometries
used in various applications. Little investigation has been done regarding
the mechanical behavior of micron-sized nanowire structures. We conduct
in situ microcompression experiments on vertically aligned dense microbundles
of 300 nm diameter single-crystalline zinc oxide nanowires to gain
insights into their structural failure. Experiments demonstrate that
bundles containing approximately 10–130 nanowires experience
two failure regimes: (1) localized noncatastrophic interfacial splitting
and (2) global structural failure. Utilizing Weibull statistics and
experimental results, we develop a technique for analyzing flaw distribution
and use it to predict the expected range of bundle failure stress.
This analysis provides guidelines for nanowire arrays’ susceptibility
to failure, sensitivity to flaw size, interfacial interactions of
constituents, and degree of alignment. This work develops insights
to understand and predict fundamental failure mechanisms in highly
aligned, dense structures.