“…1,2 The bubble electrospinning 3,4 was invented by inspiration of the spider spinning, and 3-D printing technology [5][6][7][8][9] can be optimized by spider's web design. It was reported that the spider spinning has the attractive property of minimal energy consumption, 2 the energy saving 10,11 and energy harvesting 12,13 are two key factors for a green earth. Spider silk has many advantages, such as high elasticity, high toughness, high water absorption, light weight and biodegradability, which make it in many fields, such as aerospace (structural materials and composite materials of artificial satellites and space suits), military (tanks, armor, aircraft, bulletproof vests and parachutes), industrial (high-strength materials, wheel casings, etc.)…”