Effect of tetrabutylammonium hydrogen sulphate on the Solution thermodynamics of thiamine hydrochloride in aqueous solutions

Volumetric and UV–Visible Spectroscopic Evaluation of Interactions between Thiamine Hydrochloride and Protic Ionic Liquids in Aqueous Solutions

“…Utilizing the Newton–Laplace equation and solution compressibility, κ s was obtained as κ s = c –2 ρ –1 . The comparison of density and speed of sound data of Th.HCl in water with the literature data are shown in Supporting Information, Figures S1 and S2. ,, The ρ and c data was used for calculating the apparent molar volumes and apparent isentropic compressibility for various binary/ternary solutions as V 2 , ϕ = [ M / ρ ] − [ false( ρ − ρ o false) / false( m ρ ρ o false) ] K s , 2 , ϕ = ( κ normals M / ρ ) − [ false( κ s ° ρ − κ s ρ o false) / false( m ρ ρ o false) ] here V 2,ϕ , M , m , ρ, and ρ o represents apparent molar volume, solute molar mass, solute molality in solution (binary or ternary), density of solution, and density of solvent (Th.HCl + H 2 O + PILs or PILs + H 2 O), respectively. In eq , κ s , κ s °, and K s,2,ϕ represents isentropic compressibility of the solutions, isentropic compressibility of pure solvent, and apparent molar isentropic compressibility of binary/ternary solutions, respectively.…”

“…The measurements were performed at p = 0.1 water with the literature data are shown in Supporting Information, Figures S1 and S2. 11,20,27 The ρ and c data was used for calculating the apparent molar volumes and apparent isentropic compressibility for various binary/ternary solutions as The results obtained showed that the V 2,ϕ, values for the investigated solute increase as the temperature and cosolute concentration increase. The interactions were evaluated better by determining the infinite dilution volumes.…”

“…This is because of their distinctive properties, which include their low melting point, wide temperature range, suitable viscosity, thermal stability, nonflammability, significant electrochemical window, negligible low vapor pressure, and extensive range of solubility for both organic and inorganic substances. − Traditional volatile organic solvents have been replaced with ionic liquids, which are considered greener and more environmentally friendly. ILs are utilized not only as solvents but also as catalysts, reagents, emulsifiers, and antisolvents in the crystallization and synthesis of APIs for the enhancement and development of drug delivery-based systems. − ILs are used in a variety of pharmaceutical processes, from synthesis to drug delivery. , ILs-drug molecule interactions are being studied to improve the existing formulations. They are allocated in the production of aqueous biphasic systems (ABS) which are substitutes for bioseparation techniques, purification, and liquid–liquid extraction.…”

Molecular Interactions of Saccharides and Their Derivatives with Thiamine HCl and Pyridoxine HCl Vitamins in Aqueous Solutions: Calorimetric, Viscometric, and NMR Spectroscopic Studies

“…7,8 Vitamin B complexes are essential nutrients which play an important role in nerve conduction, carbohydrate metabolism, cell growth, the digestive system, and normal heart activity. 9 It is known that vitamins are not produced within the body; thus, they must be taken through the diet and have been used as nutrient supplements in feed industries, medicines, cosmetics, as well as additives to enhance the nutritional values of different food products. Important vitamins such as thiamine HCl (vitamin B1) and pyridoxine HCl (vitamin B6) are known to cure diseases like tuberculosis and beriberi.…”