2002
DOI: 10.1016/s0021-9673(01)01535-7
|View full text |Cite
|
Sign up to set email alerts
|

Effect of the organic modifier concentration on the retention in reversed-phase liquid chromatography

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

0
31
0
2

Year Published

2004
2004
2022
2022

Publication Types

Select...
8

Relationship

0
8

Authors

Journals

citations
Cited by 67 publications
(33 citation statements)
references
References 44 publications
0
31
0
2
Order By: Relevance
“…Basically, Eq. (1) relies on the assumption that the analyte participates in the partition between mobile and stationary phase as a sole species, as not being involved in any secondary chemical equilibrium in mobile phase [17,18]. Deviation from van't Hoff temperature dependence of studied compounds can be explained by tautomeric interconversions in mobile phase in which they are participating.…”
Section: Data Modelingmentioning
confidence: 99%
“…Basically, Eq. (1) relies on the assumption that the analyte participates in the partition between mobile and stationary phase as a sole species, as not being involved in any secondary chemical equilibrium in mobile phase [17,18]. Deviation from van't Hoff temperature dependence of studied compounds can be explained by tautomeric interconversions in mobile phase in which they are participating.…”
Section: Data Modelingmentioning
confidence: 99%
“…This is behavior that is opposite to that in RPLC and has characteristics typical of HILIC [28,52,53]. Perhaps, it might be a complex retention process composed of partitioning of solutes between a surface water layer and the bulk mobile phase, surface adsorption and electrostatic interactions [6,[54][55][56]. Hence, the retentive property at high levels of organic solvents reflected the hydrophilic nature of the stationary phase.…”
Section: The Effect Of Acetonitrile Content On Retentionmentioning
confidence: 96%
“…Several three-parameter equations have been suggested by some investigators, such as those presented by Pappa-Louisi [21]: …”
Section: Theorymentioning
confidence: 99%