The performance of cementitious composites reinforced with fibres or/and bars depends on the bond strength between inclusion and cementitious matrix. The nature of formation of fibre‐matrix bond is crucial for enhancing the reliability and utilisation of reinforced composites. The research provides a review on the recently published result about the changes in the microstructure of cement matrix surrounding steel fibres with different surface roughness, using a scanning electron microscope (SEM) coupled with k‐means clustering algorithm for image segmentation. The debonding pattern of the fibre‐matrix bond after the tensile loading cycles was discussed by observing the amount of adhered cement paste to the pulled out fibre surface with SEM. Therefore, analysis of SEM images enabled to explain the connection between the micro‐scale properties of cement paste and fibre after application of cyclic loading.