Resembling a distinctive stratum of chemical transformations,
photocatalysis
employs the energy from the Sun to drive thermodynamically uphill
reactions by simply emulating what nature does bestphotosynthesis;
photocatalysis therefore promises a sustainable solution to circumvent
the increasingly tense environmental threats and energy crisis. In
this contribution, we shed light on the opportune design and development
of a dual Z-scheme photocatalytic system with homo–hetero junctions
using mixed-phase red/black phosphorus (RP/BP) and tungsten oxide
(WO3) in regulating charge steering for directional electron–hole
transfer to drive efficient CO2 reduction. Fascinatingly,
the ternary composite material (RP/BP@WO3) displayed a
striking enhancement in optical absorption capacity, which extended
from the ultraviolet up to the near-infrared region, rendering its
capability of maximizing photon absorption to power efficacious photocatalytic
reactions. With the endowment of two effective charge transport pathways
that feature a cascade electron flow profile, the RP/BP@WO3 dual Z-scheme photocatalyst achieved a CH4 yield of 6.21
μmol g–1 over 6 h under visible light illumination,
whereas the pristine counterparts, namely, RP, WO3, and
RP/BP, did not produce any CH4 yield. The amalgamation
of RP/BP homojunction as the reduction catalyst and WO3 as the oxidation catalyst intriguingly serve as a complement to
provoke CO2 reduction to CH4. The phenomenon
is explicated by the formation of an arrow-up dual Z-scheme system
that is governed by an internal electric field from the homo–hetero
junctions which bestows strong redox potentials and favors the separation
and transfer of photoinduced charge carriers, leading to increased
participation of electron–hole pairs in redox reactions for
improved photoconversion performance.