2023
DOI: 10.1002/aocs.12784
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Effect of the water content and the lengthening of fatty acids chain on the iCALB‐catalyzed esterification in deep eutectic solvents

Lorena Maurente,
Nicolás Callejas,
Elisa Volonterio
et al.

Abstract: Four Deep Eutectic Solvents (DES) based on choline chloride (ChCl) and different hydrogen bond donors (1,4‐butanediol, glycerol, isosorbide, and urea) were tested as reaction medium for the immobilized Candida antarctica B (iCALB) lipase‐catalyzed esterification of fatty acids with n‐butanol. Although the strong hydrogen bonds between DES components were expected to lower their reactivity, all except urea, competed in the esterification reaction. To study the effect of acyl group donor and water, different cha… Show more

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