and E. A. PakshverThe thermal characteristics of para-aramid, polyoxadiazole, and polyimide fibres were comparatively investigated by dynamic thermogravimetric analysis, differential scanning calorimetry, and thermomechanical analysis. It was shown that thermooxidative degradation of these types of fibres began at 400-450°C and intensified at higher temperatures. The fibres investigated are characterized by size stability up to the initial temperature of thermooxidative processes (400-450°C). With respect to thermal stability, these fibres are in the following order: polyimide > polyoxadiazole, and carbocyclic para-aramid fibres. The correlation of the "hydrogen index" I H and "aromaticity index" I Ar for thermostable fibres with their thermal stability was demonstrated.Among the fibres and fibre materials with extreme characteristics, aromatic ultrastrong and thermostable fibres and thread occupy the leading position and world production is estimated at more than 70,000 tons a year and continues to increase. The materials made from them are designed for prolonged use in the most critical articles at high loads and/or temperatures: in structures in modern transportation (especially aircraft), items for occupational protection, rescue equipment in transportation or in dangerous plants, etc. As a function of the application, these materials and the items made from them must satisfy additional special requirements: preservation of size and shape at high temperatures, resistance to open flames, preservation of elevated electrical insulation indexes, etc. Many types of fibres and thread satisfy these indexes, and the following are made from them:-thermostable polyimide fibres and thread (PI-PM) which have high flame resistance and are highly thermostable dielectrics;-thermostable polyoxadiazole (POD) fibres and thread used in protective clothing and for high-temperature filtration of gases; -thermostable, high-strength and high-modulus para-aramid fibres and thread made of poly(p-phenylene terephthalamide) (PPTA), which have the low deformability necessary for highly loaded textile articles and composites.A comparison and comparative analysis of the functional characteristics in prolonged exposure to high temperatures are the most important questions in optimizing the use of these fibres and fibre materials. However, such data are only reported in the literature for the strength indexes, estimated at 20 and 250 or 300°C [1][2][3][4][5][6][7]. In some studies, both the strength and the change in the strength in thermal aging and the thermal characteristics of the individual types of aromatic fibres have been compared [8][9][10][11][12][13][14]. The attempts to compare the few data from different researchers were very approximate due to the methodological differences and indeterminacy in selection of the samples.We found no published comparative studies of thermooxidative degradation of different kinds of aromatic fibres/thread, although these data are extremely important in optimizing their selection for different type...