Commercially available SnO2 powder is used in the form of pellets. Copper is deposited on SnO2 pellets by ablation with Excimer laser using copper target to increase their sensitivity for CO and LPG. The samples were ablated for a variable time of 1, 1.5, 2, and 2.5 min and sintered at 500°C, 550°C, 600°C, and 650°C for 5 h, respectively. The samples that were ablated for 1.5 min and sintered at 550°C show the highest sensitivity for CO and LPG at 180°C and 280°C, respectively. The structural characterization was carried out using X‐ray diffraction, scanning electron micrography, and energy‐dispersive X‐ray spectroscopy.