2011
DOI: 10.1103/physrevb.83.132502
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Effect of varying iron content on the transport properties of the potassium-intercalated iron selenideKxFe2y

Abstract: We report the successful growth of high-quality single crystals of potassium intercalated iron selenide K x Fe 2−y Se 2 by Bridgeman method. The effect of iron vacancies on transport properties was investigated by electrical resistivity and magnetic susceptibility measurements. With varying iron content, the system passes from semiconducting/insulating to superconducting state. Comparing with superconductivity, the anomalous "hump" effect in the normal state resistivity is much more sensitive to the iron defic… Show more

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Cited by 134 publications
(88 citation statements)
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“…We seek for the commonality between the iron chalcogenides and pnictides based on the observation that the parent compound of the alkaline iron selenides are anti-ferromagnetic insulators 6,14 . These insulating selenides contain Fe vacancies that are ordered in the Fe-square lattice, so that the Fe valence is kept at þ 2.…”
Section: Resultsmentioning
confidence: 99%
“…We seek for the commonality between the iron chalcogenides and pnictides based on the observation that the parent compound of the alkaline iron selenides are anti-ferromagnetic insulators 6,14 . These insulating selenides contain Fe vacancies that are ordered in the Fe-square lattice, so that the Fe valence is kept at þ 2.…”
Section: Resultsmentioning
confidence: 99%
“…3 and 4. However, the hump phenomenon has been found in other iron-selenide, K x Fe 2−y Se 2 , superconductors 40,41 , but it was not present in FeAs-based superconductors, where resistivity data for the pristine or doped compound exhibit a metallic behavior over the entire temperature range 42 . More interestingly, T c , T s and the maximum in dρ/dT are suppressed by increasing the Co or S-doping in FeSe.…”
Section: Structural Transitionmentioning
confidence: 95%
“…A x Fe 2−y Se 2 (A = K, Rb, and Cs) Precursor A x Fe 2−y Se 2 (A = K, Rb, and Cs) single crystals used as precursors can be obtained using self-flux, Bridgman, and optical floating-zone (OFZ) crystal growth methods [54][55][56][57][58][59][60][61][62][63]. Figure 1a,b show the schematic illustrations of the self-flux and Bridgman growth methods, respectively.…”
Section: Crystal Growthmentioning
confidence: 99%