1993
DOI: 10.1021/ie00015a020
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Effect of water presence on methyl tert-butyl ether and ethyl tert-butyl ether liquid-phase syntheses

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Cited by 62 publications
(57 citation statements)
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“…Besides ethers and primary alcohols, tertiary alcohols such as TBA and tert-amyl alcohol (TAA) are also considered suitable additives due to their low volatility and their potential to reduce aldehyde formation from the combustion of gasoline-ether mixtures [17].…”
mentioning
confidence: 99%
“…Besides ethers and primary alcohols, tertiary alcohols such as TBA and tert-amyl alcohol (TAA) are also considered suitable additives due to their low volatility and their potential to reduce aldehyde formation from the combustion of gasoline-ether mixtures [17].…”
mentioning
confidence: 99%
“…So, it seems that MTBE producers are mainly interested in the flexibility of MTBE/ETBE plants (Anderson, 1988;Forestiere et al, 1991). Another factor that could reduce ethanol cost is the possibility of using azeotropic ethanol (96.5 wt %) (Bakas et al, 1990;Cunill et al, 1993) or subazeotropic ethanol (80-85 wt % ) 0888-5885/94/2633-0581$04.50/0 (Jayadeokar and Sharma, 1992) as a raw material for ETBE production.…”
mentioning
confidence: 99%
“…Evidently as a result of its presence in the reaction mixture the activity of the catalysts for the synthesis of ETBE reduced as has been noted elsewhere [14,15]. At the same time it can be anticipated that the presence of water in a reaction mixture should facilitate processes which require the presence of highly acid centers and it may counteract the deactivating influence of hydrogen.…”
Section: Resultsmentioning
confidence: 80%