Although concrete and cement-based materials are the
most engineered
materials employed by mankind, their potential for use in daytime
radiative cooling applications has yet to be fully explored. Due to
its complex structure, which is composed of multiple phases and textural
details, fine-tuning of concrete is impossible without first analyzing
its most important ingredients. Here, the radiative cooling properties
of Portlandite (Ca(OH)2) and Tobermorite (Ca5Si6O16(OH)2·4H2O)
are studied due to their crucial relevance in cement and concrete
science and technology. Our findings demonstrate that, in contrast
to concrete (which is a strong infrared emitter but a poor sun reflector),
both Portlandite and Tobermorite exhibit good radiative cooling capabilities.
These results provide solid evidence that, with the correct optimization
of composition and porosity, concrete can be transformed into a material
suitable for daytime radiative cooling.