To explore whether a flat-band system can accommodate superconductivity, we consider repulsively interacting fermions on the diamond chain, a simplest quasi-one-dimensional system that contains a flat band. Exact diagonalization and the density-matrix renormalization group (DMRG) are used to show that we have a significant binding energy of a Cooper pair with a long-tailed pair-pair correlation in real space when the total band filling is slightly below 1/3, where a filled dispersive band interacts with the flat band that is empty but close to EF . Pairs selectively formed across the outer sites of the diamond chain are responsible for the pairing correlation. At exactly 1/3-filling an insulating phase emerges, where the entanglement spectrum indicates the particles on the outer sites are highly entangled and topological. These come from a peculiarity of the flat band in which "Wannier orbits" are not orthogonalizable.PACS numbers: 74.20. Rp, 71.10.Fd, 67.85.Lm Introduction-While fascinations with unconventional superconductivity arising from electron correlation continue to increase, as exemplified by the high-T C cuprates and iron-based superconductors, a next question to ask is whether there exists an avenue where we have superconductivity with another pairing mechanism. Namely, in the superconductivity in correlated electron systems, the standard viewpoint is that the interaction mediated by spin fluctuations glues the electrons into anisotropic pairs such as d-wave or s +− , where the nesting of the Fermi surface dominates the fluctuation, hence the superconductivity. To look for a different class of models, one intriguing direction is to consider correlated systems on flat-band lattices that contain dispersionless band(s) in their band structure. This is because, regardless of the Fermi energy residing on or off the flat band, we cannot define the Fermi surface for the flat band. In other words, we cannot apply, in one-dimensional cases, TomonagaLuttinger picture for the states around E F even with multichannel g-ology unlike the case of ladders. Thus, if superconductivity does arise, this might harbor a mechanism in which the flat band plays a role distinct from the conventional, nesting-dominated boson-exchange mechanisms.In the field of ferromagnetism, on the other hand, there is a long history for the study of flat-band ferromagnetism 1-3 , which is distinct from the conventional (Stoner) ferromagnetism.The ferromagnetic ground state is rigorously shown for arbitrary repulsive interaction 0 < U ≤ ∞ when the flat band is half-filled. The flat-band lattice models are conceived as Lieb model 1 with different numbers of A and B sublattice sites, or Mielke and Tasaki models 2,3 such as kagome lattice. A speciality of these flat-band lattices appears as an anomalous situation that Wannier orbitals cannot be orthogonalized, which is called the connectivity condition for the density matrix 4 . This immediately dictates that the flat band arises from interferences, hence totally different from the atomic (ze...