“…Several techniques for determining the elemental composition, depth profile or surface morphology have been used. Rutherford back-scattering spectrometry (RBS), 1 accelerator mass spectrometry (AMS), 2 X-ray photoelectron spectroscopy (XPS), 3 Auger electron spectroscopy (AES), 4 scanning tunnelling microscopy (STM), 5 atomic force microscopy (AFM), 6 Raman spectroscopy 7 and infrared spectroscopy (IR) 8 have been applied satisfactorily as surface characterisation tools. Laserna and co-workers have proposed the use of laser-induced breakdown spectrometry (LIBS) for the surface analysis with in-depth and lateral resolution of different samples of interest in industrial and environmental fields, such as photogalvanic cells, 9,10 silicon wafers, 11,12 coated steels, [13][14][15][16] photovoltaic solar cells, 17 catalytic converters 18 and pigments.…”