Abstract. In this paper we present an investigation of the spatial and temporal
variability of street-level concentrations of NO2 in Hong Kong as
an example of a densely populated megacity with heavy traffic. For the study
we use a combination of open-path remote sensing and in situ measurement
techniques that allows us to separate temporal changes and spatial patterns
and analyse them separately. Two measurement campaigns have been conducted,
one in December 2010 and one in March 2017. Each campaign lasted for a week
which allowed us to examine diurnal cycles, weekly patterns as well as
spatially resolved long-term changes. We combined a long-path differential
optical absorption spectroscopy (DOAS) instrument with a cavity-enhanced DOAS
and applied several normalizations to the data sets in order to make the
different measurement routes comparable. For the analysis of long-term
changes we used the entire unfiltered data set and for the comparison of
spatial patterns we filtered out the accumulation of NO2 when
stopping at traffic lights for focusing on the changes of NO2
spatial distribution instead of comparing traffic flow patterns. For the
generation of composite maps the diurnal cycle has been normalized by scaling
the mobile data with coinciding citywide path-averaged measurement results. An overall descending trend from 2010 to 2017 could be observed, consistent
with the observations of the Ozone Monitoring Instrument (OMI) and the
Environment Protection Department (EPD) air quality monitoring network data.
However, long-term difference maps show pronounced spatial structures with
some areas, e.g. around subway stations, revealing an increasing trend. We
could also show that the weekend effect, which for the most part of Hong
Kong shows reduced NO2 concentrations on Sundays and to a lesser degree on
Saturdays, is reversed around shopping malls. Our study shows that
spatial differences have to be considered when discussing citywide trends
and can be used to put local point measurements into perspective. The
resulting data set provides a better insight into on-road NO2
characteristics in Hong Kong, which helps to identify heavily polluted areas
and represents a useful database for urban planning and the design of
pollution control measures.