The inefficient luminescence performance
of Ce3+ activated
glasses is primarily responsible for their commercial failure compared
to the Ce3+ activated crystalline materials that are widely
used as phosphors and scintillators. We observed that this behavior
is explicitly related to the intrinsic characteristics of the host
material. Here, we present a systematic study on Ce3+ luminescence
in amorphous borate glass and make a comparison with the well-known
polycrystalline Y3Al5O12:Ce3+ (YAG:Ce) phosphor. In borate glass, Ce3+ exhibits blue
luminescence with quantum yield (QY) of about 42%, whereas the QY
is more than 85% in YAG:Ce ceramic that exhibits yellow luminescence.
This typical behavior has been discussed in terms of the site rigidity
of dopant ions in the glassy and crystalline hosts, and its influence
on the Ce3+ 5d
j
states’
crystal field splitting, Stokes shift, and the centroid shift, as
well as the probability of thermal ionization, host’s intrinsic
absorption, and the influence of Ce4+ impurity presence
in the respective host materials. This study gives a quantitative
understanding of host’s contribution on dopant’s luminescence
properties and thereby provides an optimization guideline, which is
highly demanding for the design of novel luminescent materials.