Effects of contact metamorphism on δ13C, δ15N, and XPS nitrogen functional forms of inertinite-rich Witbank coals (South Africa): Indications for possible alteration by hydrothermal fluids

Moroeng, Ofentse M.

doi:10.1016/j.chemgeo.2022.121135

Cited by 7 publications

(1 citation statement)

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“…Ghosh et al (2020) used Raman spectroscopy, FTIR, and X-ray photoelectron spectroscopy to study the microstructural framework of coal in Langanji and Jaria basins and the Himalayas. Moroeng (2022) used X-ray photoelectron spectroscopy (XPS) to analyze the effect of contact metamorphism on N in Wittbank coal (South Africa). Jaiswal and Pal (2020) used XRD, XPS, FTIR, and high-resolution transmission electron microscopy (HRTEM) to characterize the structural characterization of Indian vitrinite-rich bituminous Karharbari coal.…”

Section: Introductionmentioning

confidence: 99%

Characteristics of coal oxidation and spontaneous combustion in Baishihu Mine, Xinjiang, China

Zhang

Zeng

2023

Front. Earth Sci.

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The characteristics of oxidized spontaneous combustion of coal can reflect the performance of coal, and an appropriate structural model can reflect it more intuitively. In this study, samples from Baishihu Coal Mine were used to study the macromolecular structure, microcrystal structure, and oxidation process of coal by X-ray photoelectron spectroscopy (XPS), carbon nuclear magnetic resonance (13C-NMR), and Fourier infrared spectroscopy (FTIR). The molecular formula C198H164O40N2 and the molecular structure model were obtained. ChemDraw and Materials Studio were used for the experimental data, and high-resolution transmission electron microscopy (HRTEM) was used to verify the aromatic ring structure built to make the constructed structural model more accurate. In the water evaporation stage, the high ring aromatic layer is converted into the low ring number. Furthermore, in the high-temperature stage, the low ring aromatic layer is transformed due to the coking and condensation reaction of the coal sample. The C element in the coal sample mainly participates in the reaction in C–C and C–H forms. The spacing and effective number of aromatic layers are relatively stable. The aggregation state of coal is a macromolecular group formed between molecules with different aromatic structures and fat structures, which is formed by the interaction of internal defects and pores of molecular groups. With the increase in the treatment temperature, water loss is heavier, oxygen absorption and weight gain are perplexing, and the value of the burnout temperature is higher. The apparent activation energy of the coal–oxygen reaction increases, and the reaction is more intricate to achieve. This study furthers the understanding of coal spontaneous combustion in this mining area, provides a reference for the prevention and control of coal spontaneous combustion.

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Section: Introductionmentioning

confidence: 99%