2002
DOI: 10.1063/1.1471368
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Effects of electron–phonon interaction and chemical shift on near-band-edge recombination in GaN

Abstract: A coherent analysis of the near-band-edge luminescence spectra of undoped and Si-doped GaN layers grown by metalorganic vapor phase epitaxy on a sapphire substrate has been performed with a model including the effect of the charge carrier–longitudinal optical (LO) phonon interaction, based on Fröhlich’s polaron theory. This model allows one to correlate the relative intensities of the phonon sidebands to the position of the zero-phonon line from which ionization energies are obtained. Moreover, central-cell co… Show more

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Cited by 14 publications
(2 citation statements)
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“…Local temperature rises are dominated by electron−phonon coupling, which transfers energy from the electron beam to the semiconductor lattice. In this case, the higher values of electron−phonon coupling constants ( S = 2.81 for GaN, , 2.16 for CdS, 1.67 for CdSe) and Debye temperatures (θ D = 600K for GaN, 219 K for CdS, and 181 K for CdSe) correlate with more efficient thermal excitation of GaN than CdS than CdSe. While differences in efficiency of thermal excitation are consistent with our findings, contributions by differences in crystalline quality and interfacial thermal conductivity cannot conclusively be dismissed.…”
Section: Resultsmentioning
confidence: 89%
“…Local temperature rises are dominated by electron−phonon coupling, which transfers energy from the electron beam to the semiconductor lattice. In this case, the higher values of electron−phonon coupling constants ( S = 2.81 for GaN, , 2.16 for CdS, 1.67 for CdSe) and Debye temperatures (θ D = 600K for GaN, 219 K for CdS, and 181 K for CdSe) correlate with more efficient thermal excitation of GaN than CdS than CdSe. While differences in efficiency of thermal excitation are consistent with our findings, contributions by differences in crystalline quality and interfacial thermal conductivity cannot conclusively be dismissed.…”
Section: Resultsmentioning
confidence: 89%
“…The usual materials for fabricating the semiconductor QW structures, for example GaAs/Al x Ga 1−x As, are ionic. Therefore, the interplay of the electron-LO-phonon interaction can cause polaron-related effects, which can change properties such as the energy and effective mass of the carrier in confined QWs [1][2][3][4][5][6][7][8][9][10][11]. However, this effect is still under consideration in real materials [11].…”
Section: Introductionmentioning
confidence: 99%