2021
DOI: 10.3390/met11111709
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Effects of Fe/Si Stoichiometry on Formation of Fe3Si/FeSi-Al2O3 Composites by Aluminothermic Combustion Synthesis

Abstract: Aluminothermic combustion synthesis was conducted with Fe2O3–Al–Fe–Si reaction systems under Fe/Si stoichiometry from Fe-20 to Fe-50 at. % Si to investigate the formation Fe3Si/FeSi–Al2O3 composites. The solid-state combustion was sufficiently exothermic to sustain the overall reaction in the mode of self-propagating high-temperature synthesis (SHS). Dependence of iron silicide phases formed from SHS on Fe/Si stoichiometry was examined. Experimental evidence indicated that combustion exothermicity and flame-fr… Show more

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Cited by 9 publications
(3 citation statements)
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“…As can be seen, the results for the free silicon sample (sample 0) are consistent with the ternary diagram. This means that the FeAl phase with the B2 structure is obtained [34].…”
Section: Resultsmentioning
confidence: 96%
“…As can be seen, the results for the free silicon sample (sample 0) are consistent with the ternary diagram. This means that the FeAl phase with the B2 structure is obtained [34].…”
Section: Resultsmentioning
confidence: 96%
“…In addition, in the mechanical alloying method, the composition of phases exceeds the solubility limit [44].…”
Section: Resultsmentioning
confidence: 99%
“…However, the feasibility of this substitution is limited by low fracture toughness of Ti-Al-Si materials, anisotropy of the thermal expansion coefficient of Ti5Si3 phase [6] and also by the fact that titanium was newly listed as a critical raw material in 2020 [1]. There were also other researches dealing with intermetallic composites running, such as aluminide -ceramics [7][8][9] or silicideceramics [10,11] or silicide-aluminide coatings [12][13][14].…”
Section: Introductionmentioning
confidence: 99%