Associated gas worth
of tens of billions of dollars is flared annually
during oil and gas production, which leads to resource waste and environmental
issues. The combustion characteristics of associated gas mixtures
with high concentrations of C2–C4 hydrocarbons,
sometimes called high-BTU gases, were examined in this study. Specifically,
adiabatic laminar flame speeds and combustion stability, including
critical heat loss at extinction, were quantified for a range of associated
gas mixtures. The study used a porous plug burner facility for stabilization
of premixed, laminar flat flames with measured heat loss from the
flames. Standoff distances of associated gas flames were measured
using CH* chemiluminescence for validation of the technique by comparison
with numerical simulations and analytical modeling, and standoff distance
was used to determine stable operating points. Laminar flame speeds
of the major component gases (methane, ethane, propane, and butane)
and three associated gas mixtures from the Bakken gas field in North
Dakota were investigated at lean to mildly rich equivalence ratios
(ϕ = 0.7–1.1). Numerical simulations were performed using
USC II and Aramco 1.3 mechanisms for comparison of numerical and experimental
laminar flame speeds of component and associated gas mixtures. Additionally,
a flame speed correlation was introduced to model the flame speeds
of these quaternary gas mixtures. Finally, a heat loss ratio was defined
through comparison of heat loss and burner firing rate, and critical
heat loss ratios were identified where these associated gas mixtures
become unstable and extinguish. Results are discussed in the context
of utilization of associated gas with high concentrations of C2–C4 alkanes.