Forest roads significantly affect sediment connectivity in mountainous catchments by contributing to the production of and disturbing the confluence of sediment-loaded runoff. This study considered forest roads as pathways and sinks of sediment-loaded runoff to understand the effects of forest roads on the confluence characteristics and sediment connectivity in mountainous a catchment using a scenario simulation. In order to determine the contribution and spatial relationship between sediment connectivity and influencing factors, this study utilized buffer analysis, an extremely randomized tree model, and multiscale geographically weighted regression. The results show that the presence of forest roads significantly changes the transport process and connectivity of runoff and sediment in the mountainous catchment. Specifically, flow length increases, but flow accumulation, upslope contributing area, and topographic index decrease with increasing distance from roads and streams. Meanwhile, the effects of roads on convergence characteristics and sediment connectivity are mainly manifested within a certain threshold that varies with different confluence characteristics. Moreover, sediment connectivity increases when considering roads as pathways and sinks of sediment-loaded runoff, especially on the upper hillslopes intercepted by roads and at the road–stream crossings. In addition, the closer the distance to the roads, the greater the impact of road on the confluence characteristics and sediment connectivity. Change in flow length is the most important factor affecting the sediment connectivity among all of the other convergence, terrain, and spatial distance characteristics. The longer the flow length, the lower the sediment connectivity. In conclusion, this study demonstrates that the altered confluence processes by roads increases the possibility that sediment-loaded runoff will be transported to the catchment outlet, which is of significance for the proper management of forest roads in mountainous catchments.