Ammonia (NH3) as an alternative carbon-free
fuel suffers
from poor combustion and emission performance, limiting its large-scale
commercial utilization in the automobile industry. It has been shown
that ammonia combustion is sensitive to operating boundary conditions
of actual engines. In this work, the effects of thermodynamic boundary
conditions (i.e., wall and intake temperature) on ammonia combustion
and emissions were investigated using an optical spark-ignition engine
with a high compression ratio. Wall and intake temperatures were regulated
by a coolant and an intake heater, respectively. The results show
that raising the wall temperature can significantly improve combustion
stability, combustion efficiency, and thermal efficiency, while intake
temperatures can enhance ammonia combustion only when the wall temperature
reaches beyond some thresholds. Combustion visualization shows that
the intake and wall temperature affect different stages of the combustion
process. Specifically, the intake temperature might predominantly
influence the early stages of combustion, whereas the wall temperature
might have a more significant impact on the entire combustion process.
Elevating the intake temperature increases the flame propagation speed,
while there are no obvious changes in terms of the wall temperature.
Flame analysis shows that a high wall temperature corresponds to a
lower flame stretch sensitivity, indicating reduced cyclic variations
in flame propagation and alleviating the possibility of flame quenching.
While a high intake temperature features a stronger flame response
to turbulence at the early stage of flame development. Besides, NH3 and N2O emissions are significantly reduced due
to the improvement of flame propagation instability and incomplete
combustion based on the crevice mechanism, but there is an increase
in NO and NO2 emissions. The chemical kinetic analysis
indicates that increasing NO
x
emissions
mainly comes from the temperature and pressure sensitivities of fuel-type
NO
x
.