“…Furthermore, this approach allows for observation of intermediate phases and order–order transitions during the annealing process. ,,, The self-assembly process of diblock copolymers has been extensively explored by real-time GISAXS studies, ,,,,, but there is limited work on the self-assembly of cyclic, branched, or multiblock polymer architectures, such as cyclic block copolymers, linear triblock terpolymers, ,,− miktoarm star terpolymers, ,, and bottlebrush copolymers. ,,, The phase behavior of multiblock polymers is more difficult to elucidate using ex situ characterization due to their additional degrees of freedom and a wider range of morphologies. These morphologies can offer additional functionality; for example, nanoscale ring structures formed from core–shell cylinders can exhibit desirable optical, electronic, and magnetic properties. ,− …”