Land use and cover change (LUCC) is an important anthropogenic forcing of the climate system. Previous studies have demonstrated that LUCC significantly impacts both mean and extreme temperatures. In this study, we explored the multimodel performance of simulating LUCC‐induced asymmetric effects on the different percentiles of maximum temperatures (Tmax) as well as the possible reasons for these effects using results from the fifth phase of the Coupled Model Intercomparison Project (CMIP5). Four state‐of‐art Earth system models (which provide the necessary data) are selected for investigating this issue. In general, all the cases of the model from the Geophysical Fluid Dynamics Laboratory show robust asymmetric responses between the 90th (TX90P) and 10th percentiles (TX10P) of Tmax, mainly due to cropland expansions, especially over India, the Sahel, and some parts of North America. However, weak and insignificant responses are shown for both the TX90P and TX10P in other models. The different changes in the Tmax variability among the models are primarily responsible for the occurrence of asymmetric features. Furthermore, by decomposing the Tmax changes over three typical regions, we analyze the potential causes for the inconsistencies among these models' results and find two crucial processes, that is, the repartitioning of the turbulent heat fluxes and the changes of the diurnal cycle variability due to LUCC. Whether these processes are pronounced determines the occurrence of the asymmetric Tmax responses. Overall, this study provides a critical clue for reducing the uncertainties of the LUCC effects on temperature extremes, which should be evaluated against observations.