Resistive Plate Counters (RPC) are employed as muon detectors in many high-rate high-energy physics experiments, such as the Compact Muon Solenoid (CMS) experiment currently under way in the Large Hadron Collider (LHC) accelerator at the European Center for Nuclear Research (CERN). A gas mixture containing C 2 H 2 F 4 , i− C 4 H 10 and SF 6 is recirculated inside the RPCs during their use and subjected to degradation due to the production of fluoride ions which limits the sensitivity of the RPCs. This paper describes a new sensor that is able to detect low concentrations of fluoride ions in gas mixtures. The sensor is made of a plastic optic fiber (POF) which is made sensitive to F − gaseous ions by means of a thin layer of a glass-like material, deposited via plasma onto the fiber core. The F − ions attack the glass-like film and alter the transmission capability of the fiber so that the detection simply requires a LED and a photodiode. The sensor exploits a cumulative response which makes it suitable for direct estimation of the total exposure to the F − ions, thus providing a tool that can be used to tune the maintenance of the gas filters. The glass-like film is deposited by means of plasma enhanced chemical vapor deposition (PECVD) of organosilicons monomers, which allows the deposition to be performed a low temperature in order to avoid damaging the fiber core.