This study investigates the magnetization mechanisms in MnZn ferrites, which are key materials in high-frequency power electronics, to understand their behavior under various sintering conditions. Employing X-ray diffraction and scanning electron microscopy, we analyzed the microstructure and phase purity of ferrites sintered at different temperatures. Our findings confirm consistent spinel structures and highlight significant grain-growth and densification variabilities. Magnetic properties, particularly the saturation magnetization (Ms) and initial permeability (μi), were explored, revealing their direct correlation with the sintering process. The decomposition of magnetic spectra into domain-wall-motion and spin-rotation components offered insights into the dominant magnetization mechanisms, with the domain wall movement becoming increasingly significant at higher sintering temperatures. The samples sintered at 1310 °C showcased superior permeability and the least loss in our investigations. This research underscores the impact of sintering conditions on the magnetic behavior of MnZn ferrites, providing valuable guidelines for optimizing their magnetic performance in advanced electronic applications and contributing to the material science field’s understanding of the interplay between sintering, microstructures, and magnetic properties.