2019
DOI: 10.1166/jnn.2019.16168
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Effects of Melting Conditions on Cerium Oxidation State and Catalytic Properties of CeO2–P2O5 Glass Systems

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Cited by 3 publications
(9 citation statements)
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“…The modified n‐CeO 2 spectrum exhibited the characteristic absorption peaks of both stearic acid and n‐CeO 2 at 2917, 2843, 1531, and 1248 cm −1 , respectively 37 . However, the peak positions were shifted to different extents, possibly due to the formation of coordination bonds or electrostatic bonds between the carboxyl group of stearic acid and Ce 3+ or Ce 4+ ions on the surface of n‐CeO 2 36,38 …”
Section: Resultsmentioning
confidence: 99%
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“…The modified n‐CeO 2 spectrum exhibited the characteristic absorption peaks of both stearic acid and n‐CeO 2 at 2917, 2843, 1531, and 1248 cm −1 , respectively 37 . However, the peak positions were shifted to different extents, possibly due to the formation of coordination bonds or electrostatic bonds between the carboxyl group of stearic acid and Ce 3+ or Ce 4+ ions on the surface of n‐CeO 2 36,38 …”
Section: Resultsmentioning
confidence: 99%
“…81‐0792), indicating high crystallinity and no inhomogeneity. The results showed that the carboxyl group of stearic acid formed coordination bonds or electrostatic bonds with Ce 3+ or Ce 4+ ions on the surface of n‐CeO 2 without affecting the crystal structure of n‐CeO 2 36,39,40 …”
Section: Resultsmentioning
confidence: 99%
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“…It was reported previously that some specific types of rear earth oxides such as CeO2 and Nd2O3 have dominant influences on the structure, mechanical and magnetic properties of glasses and glass ceramics [1][2][3][4][5]. A number of previous studies have been performed to shed some light on the practical and manufactured uses of glasses containing cerium oxide [6].…”
Section: Introductionmentioning
confidence: 99%
“…In addition, cerium oxide, which has been reported to be used as decolorizing glass and eye protective glasses [6,7], has been further commercially used since it has been established that cerium has a clear use, depending on its material, as an excellent ultra-violet absorption. Recently, several experimental results have been carried out on cerium silicate [8] and borate glasses [9], suggesting that CeO2 enters the host glass network as an intermediate, both as a glass modifier and as a former at normal circumstances [1][2][3][4]8,9]. Under excessive conditions, such as exposure the glass to irradiation processes, the irradiated glass becomes unusable for optical applications.…”
Section: Introductionmentioning
confidence: 99%