In the paper, we synthesized amorphous NiCoB nanoparticles
by a
simple chemical reduction method and employed them as high-activity
catalysts to considerably improve the hydrogen storage properties
of MgH2. The MgH2–NiCoB composite quickly
absorbed 3.6 wt % H2 at a low temperature of 85 °C
and released 5.5 wt % H2 below 270 °C within 600 s.
It is worth noting that the hydrogenation activation energy was reduced
to 33.0 kJ·mol–1. Detailed microstructure analysis
reveals that MgB2, Mg2Ni/Mg2NiH4, and Mg2Co/Mg2CoH5 were
in situ generated during the first de/absorption cycle and dispersed
at the surface of NiCoB. These active ingredients created lots of
boundary interfaces to facilitate the hydrogen diffusion and destabilize
the Mg–H bonds, thus decreasing the kinetic barriers. This
work provides support for a promising catalytic effect of amorphous
NiCoB on de/absorption reactions of MgH2, showing new ways
for designing Mg-based hydrogen storage systems toward practical application.