“…Unitl now, several studies have been conducted to restrict the unsuitable metal-moulds reactions by changing the casting parameters [3-5,7,8] and using different shell materials and inhibitors [6,9-13]. Silica, alumina, and zircon-based moulds illustrated effective reaction behaviour, due to having high-temperature melting points and free energy [3,5,8-11,14]. Moreover, utilising inhibitors such as silica-free binders, KBF 4 , and NaBF 4 could enhance the reaction resistance of metal–mould [6,13,14].…”