Melting/freezing temperature curves are studied for the single-component Ga and bimetallic eutectic alloys Ga-In, Ga-Sn, Ga-Zn, and Ga-Al in small-size cells. These phase-transition studies were conducted at VNIIOFI in order to design small-size fixed-point devices for metrological monitoring of temperature sensors on autonomous (e.g., space borne) platforms. The results show that Ga and some Ga-based eutectic alloys in small cells can be used as melting fixed points. The repeatability of melting temperatures of Ga, Ga-In, Ga-Sn, and Ga-Zn fixed points is studied. The effects of the concentration of the second element of Ga-based eutectic alloys and the thermal history on the melting plateau's shape and the melting temperature are studied.